Infrared absorption features due to ClO in the lower stratosphere have been identified from groundbased solar absorption spectra taken from Aberdeen, U.K. (57° N, 2° W) on 20 January 1995. A vertical column abundance of 3.42 (±0.47)×1015 molec cm-2 has been derived from 13 independent absorption features in the P and R branches of the (0–1) vibration-rotation band of 35ClO, spanning the spectral region 817–855 cm-1. The observed absorption features are consistent with very high levels of ClO (approximately 2.6 parts per billion by volume (ppbv)) in the altitude range 16–22 km. A comparison of this profile with a 3D chemical transport model profile indicates the observation was made inside the polar vortex and shows good qualitative agreement but the model underestimates the concentrations of ClO. Simultaneous measurements of other species were made including HCl, HF and ClONO2. These columns yield a value for HCl+ClONO2+ClO of 7.02±0.65×1015 molec cm-2. This is lower than the total inorganic chlorine (ClOy) column of 10.7±1.6×1015 molec cm-2 estimated from mean measured (HCl+ClONO2)/HF ratios together with in-vortex HF measurements. The discrepancy is probably due to significant amounts of the ClO dimer (Cl2O2) in the lower part of the stratosphere. The measurements of highly elevated levels of ClO are used to estimate O3 loss rates at the 400, 475 and 550 K levels making assumptions about the probable distribution of ClO and Cl2O2. These are compared with loss rates derived from ozone sonde data. 相似文献
Studying long term-evolution of gravitational slope evolution is a key to understanding deep-seated landslide processes. This paper deals with three large Deep-Seated Landslides (DSLs) at a front of a subalpine meridional chain, on the “La Marbrière” slope near the town of Grasse (Alpes-Maritimes, France). The geological framework controlling the stability and morphology of the DSLs is associated with thick and tamped Triassic layers of mudstone with gypsum overlain by highly faulted Jurassic limestone. Gravitational deformation affects the entire slope, involving a movement of about 1.1 × 108 m3 of rock material. It creates large disturbances in landscape morphology, such as scarps, counter-slope scarps, trenches and other typical gravitational morpho-structures. Geomorphological mapping coupled with deep electrical resistivity tomography (ERT) reveals a strong correlation between these morpho-structures and inherited brittle tectonic features. This observation relies on spatial and geometrical relations (on the surface and at the depth of more than 150 m, checked by ERT) between the most persistent fault and the gravitational morpho-structures. The specific distribution of the morpho-structures on the basis of their morphological typologies and variations in the stage of evolution of three DSLs provides an interpretation of their kinematics during the last 400 ka. It appears that soft substratums combined with inherited persistent anisotropies are key factors in the development of the DSLs. Indeed, outflow of mudstone due to the lithostatic pressure imposed by individual limestone compartments has led to general slope subsidence. Then, a progressive toppling of a rock mass may have led to the catastrophic rock collapse along bedding planes.The evolution of the DSLs can be divided into three distinct stages represented by three zones: a young collapse stage (zone 1), a pre-collapse stage (zone 2) and an old mature stage (> 400 ka, zone 3). As the DSLs occur on the same slope and in the same geological context, this area offers interesting perspectives for understanding factors controlling the long-term gravitational evolution of slopes. 相似文献
After a few years of research, the observation and the analysis of the deep-seated landslides suggest that these are mainly controlled by tectonic structures, which play a dominant role in the deformation of massif slopes. The La Clapière deep-seated landslide (Argentera Mercantour massif) is embedded in a deep-seated gravitational slope deformation affecting the entire slope, and characterized by specific landforms (trenches, scarps??). Onsite, the tangential displacement direction of the trenches and the scarps are controlled by the tectonic structures. The reactivation of the inherited fault in gravitational faults create a gouge material exposed to an additional mechanical and chemical weathering as well as an increased of leaching. The displacement of these reactivated faults gets increasingly important around the area of the La Clapière landslide and this since 3.6?ka BP. In this study, mechanical analysis and grain size distributions were performed and these data were analysed according to their proximity the La Clapiere landslide and times of initiation of the landslide by 10Be dating. Triaxial test results show that the effective cohesion decreases and the effective angle of internal friction increases from the unweathered area to the weathered area. The whole distribution of the grain size indicates that the further the shear zone is open or developed, the further the residual material loses its finest particles. This paper suggests that the mechanical evolution along the reactivated fault is influenced by the leaching processes. For the first time, we can extract from these data temporal behaviour of the two main mechanical parameters (cohesion and angle of internal friction) from the beginning of the La Clapiere landslide initiation (3.6 ka BP) to now. 相似文献
A Marine Isotope Stage (MIS) 3/early MIS 2 section from a structural high along the east coast of the North Basin of Lake Baikal was analysed for diatoms, C/N ratios, and organic carbon isotope ratios. Diatoms were present throughout MIS 3 and early MIS 2, with high concentrations of the planktonic taxa Cyclotella sp. c.f. gracilis between 54 and 51.5 kyr BP indicating relatively warm, interstadial, conditions. Following a %TOC inferred climatic cooling between 43.2 and 39.1 kyr BP, evidence of a more muted δ13C(organic) and %TOC inferred climatic warming from c. 39.1–34.7 kyr BP coincides with a period of very high diatom concentrations, indicating high aquatic productivity, at the Buguldeika Saddle in the South Basin of Lake Baikal. No evidence exists for a ‘Kuzmin’ catchment erosional event in the North Basin during MIS 3. This, however, may reflect the location of the coring site away from major riverine inputs. Abrupt climatic cooling at the culmination of both warm phases in the North Basin are associated, on the basis of the palaeomagnetic age-model and correlations to existing sites in Lake Baikal, with the initiation of Heinrich events 5 (c. 50 kyr BP) and 4 (c. 35 kyr BP), respectively, in the North Atlantic. The amount of organic material declines across the MIS 3/MIS 2 transition while constant C/N ratios suggest organic material to be predominantly derived from phytoplankton. An increase in δ13C(organic) at the MIS 3/MIS 2 transition may therefore indicate changes in aquatic productivity, pCO2 or the inorganic carbon pool. 相似文献
Landslides are the main secondary effects of earthquakes in mountainous areas. The spatial distribution of these landslides is controlled by the local seismic ground motion and the local slope stability. While gravitational instabilities in arid and semi-arid environments are understudied, we document the landslides triggered by the Sarpol Zahab earthquake (November 12, 2017, Mw7.3, Iran/Iraq border), the largest event ever recorded in the semi-arid Zagros Mountains. An original earthquake-induced landslide inventory was derived, encompassing landslides of various sizes and velocities (from rapid disrupted rockfalls to slow-moving coherent landslides). This inventory confirms the low level of triggered landslides in semi-arid environments. It also displays clear differences in the spatial and volumetric distributions of earthquake-induced landslides, having 386 rockfalls of limited size triggered around the epicenter, and 9 giant (areas of ca. 106 m2) active and ancient deep-seated landslides coseismically accelerated at locations up to 180 km from the epicenter. This unusual distant triggering is discussed and interpreted as an interaction between the earthquake source properties and the local geological conditions, emphasizing the key role of seismic ground motion variability at short spatial scales in triggering landslides. Finally, the study documents the kinematics of slow-moving ancient landslides accelerated by earthquakes, and opens up new perspectives for studying landslide triggering over short (~?1–10 years) and long-time (~?1000–10,000 years) periods.
This paper discusses the development and implementation of a method that can be used with multi-decadal Landsat data for computing general coastal US land use and land cover (LULC) maps consisting of seven classes. With Mobile Bay, Alabama as the study region, the method that was applied to derive LULC products for nine dates across a 34-year time span. Classifications were computed and refined using decision rules in conjunction with unsupervised classification of Landsat data and Coastal Change and Analysis Program value-added products. Each classification’s overall accuracy was assessed by comparing stratified random locations to available high spatial resolution satellite and aerial imagery, field survey data and raw Landsat RGBs. Overall classification accuracies ranged from 83 to 91% with overall κ statistics ranging from 0.78 to 0.89. Accurate classifications were computed for all nine dates, yielding effective results regardless of season and Landsat sensor. This classification method provided useful map inputs for computing LULC change products. 相似文献